Corrosion Inhibition of Mild Steel in Sodium Chloride Solution by Nickel Complex of 1-(8-hydroxy quinolin-2yl-methyl) Thiourea

Authors

  • S. S. Syed Abuthahir Post Graduate & Research Department of Chemistry Jamal Mohamed College, Tiruchirappalli 620 020, India
  • K. Vijaya Department of Chemistry, PSNA College of Engineering and Technology, Dindigul, India
  • A. Jamal Abdul Nasser Post Graduate & Research Department of Chemistry Jamal Mohamed College, Tiruchirappalli, India
  • C. Karthikeyan RVS School of Engineering and Technology, Dindigul-624 005, Tamilnadu, India

DOI:

https://doi.org/10.53555/nnas.v2i2.685

Keywords:

Corrosion inhibition, Mild Steel, Polarization, UV-Visible, spectroscopy, Transition metal complex, SEM, EDAX and Biocidal Efficiency

Abstract

The Corrosion inhibition efficiency of an inhibitor namely Nickel complex of 1-(8-hydroxy quinolin-2yl methyl) thiourea (Ni-HTF) in controlling corrosion of mild steel immersed in aqueous solution containing 60 ppm Cl- has been investigated by polarization method. The formulation consisting of 60 ppm of Cl- and 50 ppm of Ni-HTF offers good inhibition efficiency of 80 %. Polarization study reveals that this formulation functions as a cathodic inhibitor. UV-Visible spectral analysis was used to detect the presence of iron-inhibitor complex. The surface morphology has been analyzed by SEM and EDAX.

References

P.B.Raja, M.G. Sethuraman, Natural products as corrosion inhibitor for metal in corrosive media a review, Mater. Lett, 62 (2008) 113-116.

M.L. Zheludkevich, K.A. Yasku, S.K. Poznyak, M.G.S. Ferreira, Triazole and thiazole derivatives as corrosion inhibitors for AA204 aluminium alloy, Corros. Sci, 47 (2005) 3368-3383.

G.Moretti, F.Guidi, G.Grion, Tryptamine as a green iron corrosion inhibitor in 0.5 M deaerated sulphuric acid, Corros. Sci, 46 (2004) 387-403.

W.J. Guo, S.H.Chen, Y.Y.Feng, C.J,Yang. Investigations of triphenyl phosphate and bis-(2-ethylhexyl)phosphate self-assembled films on iron surface using electrochemical methods, Fourier transform infrared spectroscopy, and molecular simulations, J. Phys. Chem, C 111 (2007) 3109-3115.

K.F.Khaled, Molecular simulation, quantum chemical calculations and electrochemical studies for inhibition of mild steel by triazoles, Electrochim.Acta, 53 (2008) 3484-3492.

I.Ahamed, M.A. Quraishi, Bis (benzimidazol-2-yl) disulphide: an efficient water soluble inhibitor for corrosion of mild steel in acid media, Corros. Sci, 51 (2009) 2006-2013.

S.A.Ali, H.A. Al-Muallem, S.U. Rahman, M.T. Saceed, Bis-isoxazolidines: a new class of corrosion inhibitors of mild steel in acidic media, Corros. Sci, 50 (2008) 3070-3077.

E.M. Sherif, S.M. Park, 2-amino-5-ethyl-1,3,4-thiadiazole as a corrosion inhibitor for copper in 3.0% NaCl solutions, Corros.Sci, 48 (2006) 4065-4079.

L. Cepak, J. Adam, T. Grygar, R. Bulanek, L. Vradman, G. Kosava-Kucerova, P.Cicmanec, P.Knotek, Oxidative dehydrogenation of ethane over vanadium supported on mesoporous materials of M41S family, Appl.Catal.A, 342, (2008) 99-106..

C.Pereira, A. Rosa Silva, A.Paula Carvalho, J. Pires, C. Freire, Vanadyl acetylacetonate anchored onto amine-functionalised clays and catalytic activity in the epoxidation of geraniol, J. Mol. Catal. A, 283, (2008) 5-14.

C. Pereira, S. Patricio, A.Rosa Silva, A.L. Magalhaes, A.Paula Carvahlo, J.Pires, Cristina Freire, Copper acetylacetonate anchored onto amine-funtionalised clays, J. Colloid interf. Sci, 316, (2007) 570-579.

S. Fujihara, Sol-gel processing of fluoride and oxyfluoride materials, in:H. Kozuka (Ed.), Handbook of Sol-Gel Science and Technology: Volume 1- Sol-Gel Processing, Kluwer Academic Publoshers, (2005) 219.

M. Cernea, O.Monnereau, P.Llewellyn, L. Tortet, C. Galassi, Sol-Gel synthesis and characterization of Ce doped- BaTiO3, J. Eur.Ceram.Soc,. 26, (2006) 3241-3246.

S.Tangwiwat, S.J.Milne, Barium titanate sols prepared by a diol – based sol-gel route, J.Non-Cryst. Solids, 351,(2005) 976-980.

H.Harms, H.P. Volkland, G. Repphun, A. Hiltpolt, O. Wanner, A.J.B. Zehnder, Action of chelators on solid iron in phosphate-containing aqueous solutions, Corros. Sci,.45, (2003)1717-1732,.

S. Hettiarachchi, Palladium acetylacetonate solution, European Patent EP0651073, (1995).

M.Gerloch, E.G.Constable, Transition Metal Chemistry, VCH Verlagsgessellschaft mbH, Weinhein, (1994)176.

Nagalakshmi. R., Rajendran. S., Sathiyabama, J., Pandiarajan, M., Lydia Christy, J., Eur. Chem. Bull, 1(17), (2012), 238.

Sahayaraja A., Nagalakshmi, R., Rajendran. S., Angelin Thangakani, J., Pandiarajan, M., Eur.Chem. Bull, 1(3), (2012) 130.

Agiladevi, S., Rajendran, S., Jeyasundari, J., Pandiarajan, M., Eur.Chem.Bull, 2 (2), (2013)503.

Rajendran, S., Sridevi, S. P., Antony, N., John Amalraj, A., Sundaravadivelu, N., Anto.Corros. Methods Mater, 52,(2005)102.

Felicia Rajammal Selvarani, Santhanalakshmi, S., Wilson sahayaraja, J., John Amalraj,A., and Rajendran, S., Bull. Electrochem, 20,(2004) 561.

Rajendran, S., Maria Joany, R., Apparao, B. V. and Palaniswamy, N., Indian J.Chem.Technol., 9, (2002) 197-200.

Rajendran s., Earnest John Peter, B. R., Peter Pascal Reces, A., John Amalraj, A. and Sundaravadivelu, M., Trans. SABST, 38(1), (2003) 11-15.

Markus Albrecht., Karen Witt., Patrick Weis., Elina Wegelius., Roland Frohlich., Inorganica Chimica Acta, 341 (2002) 25-32.

Gopi D., Manomozhi S., Govindaraju K M., Manisankar P., Rajeswari S., “Surface and Electrochemical characterization of pitting corrosion behavior of 304 stainless steel in ground water media,” Journal of Applied electrochemistry, 37, (2007)439-449.

Amin M A., Abd El-Rehim S S., El-Sherbini E F F., Bayoumi R S, “The inhibition of low Carbon steel corrosion in hydrochloric acid solutions by succinic acid. Part I. Weight loss,Polarization, EIS, PZC, EDX and SEM studies,” Electrochimica Acta, 52, (11), (2007) 3588-3600.

Amin M A., Abd El-Rehim S S.,Abdel- Fatah, “Electrochemical frequency modulation and inductively coupled plasma atomic emission spectroscopy methods for monitoring corrosion rates and inhibition of low alloy steel corrosion in HCl solutions and a test for validity of the Tafel extrplotation method,” Corrosion Science, 51, (4) (2009) 882-894.

Rahim S S A., Hazzazi O A., Amin M A., Khelad K F., “On the corrosion inhibition of low carbon steel in concentrated sulphuric acid solutions. Part I: chemical and electrochemical (AC and DC) studies,” Corrosion Science, 50, no. 8, (2008) 2258-2271.

Migahed M A., Azzam E M S., Morsy S M J., “Electrochemical behavior of carbon steel in acid chloride solution in the presence of dodecyl cysteine hydrochloride self-assembled on gold nanoparticles,” Corrosion Science, Vol. 51, no, 8, (2009) 1636-1644.

Jackie Reynolds/Mark Farinha., Richland College, (2005).

Downloads

Published

2015-02-28

How to Cite

Abuthahir, S. S. S., Vijaya, K., Abdul Nasser, A. J., & Karthikeyan, C. (2015). Corrosion Inhibition of Mild Steel in Sodium Chloride Solution by Nickel Complex of 1-(8-hydroxy quinolin-2yl-methyl) Thiourea. Journal of Advance Research in Applied Science (ISSN 2208-2352), 2(2), 21-27. https://doi.org/10.53555/nnas.v2i2.685